Stains

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Miscellaneous

Notes

Thousands of body and glaze stains are available from dozens of stains companies around the world. Some companies have been in business for a hundred years or more, many specialize in creating products for a particular manufacturing sector. Some companies have multinational distribution networks, others will deal directly with small companies. Most companies have technical staff and research facilities to handle a wide range of color problems.

Stains are fired blends of metal and ceramic oxides that have been reground into a fine powder. Stains containing otherwise toxic oxides can be employed without significant dangers. This is the first aspect of something that stains have that coloring oxides don't: stability. A second aspect of stability is that stains produce much more consistent and repeatable color than using raw oxide colors.

Stains are most popular at lower temperatures where colors tend to be brighter. However most stains can be used right up to high fire. Premixed low fire glazes are typically made by blending stains and commercial frits and other than following firing instructions, users of these products give little thought to the technical challenges that were overcome to produce them. This is a third key advantage of stains: the ability to target a specific color. Many ceramic color shades (i.e. reds) are difficult to achieve and beyond the abilities of end users.

While many stains are 'standard' and their composition is well known across the industry, others are proprietary. Stain companies don't release the exact makeup of stains but they do tell us the 'system'. For example, a green stain might contain chrome, cobalt and silica and be labeled 'CrCoSi'. Although silica is not a colorant itself, it is included to create a stable silicate crystal structure with the other two.

Stain companies often supply multiple products to produce a given color using different oxide systems (i.e. chrome-tin pink, manganese-alumina pink). Various factors like the base glaze chemistry, color shade, temperature, and end use determine the system you should choose. Knowing how to calculate the oxide makeup of a glaze or dealing with a stain company that provides good service are key factor to being able to troubleshoot color problems with stains.

Thus stains do not come with a 'unconditional color guarantee'. The shade produced depends on many of factors including the host glaze chemistry, on/over/underglaze use, glaze thickness, amount of opacifier, firing temperature, etc. Achieving colors with stains is certainly easier, but it is not a 'no-brainer'. Certain systems are quite flexible and produce color in many kinds of glazes (ie. cobalt silicate). Other systems either require that certain oxides be present in the host glaze in minimum amounts or others not be present at all. The symbiosis of host glaze chemistry and stain, for example, can be demonstrated with chrome-tin stains. They will not develop color if zinc is present or if there is inadequate calcia. It is common to hear people say that their pink stain 'burned out', but generally the stain is being used in an incompatible glaze base. Another interesting demonstration of these factors is the color chart of a typical stain company. These charts show the stain used in one or more fritted base glazes that are selected to be compatible with as many of the colors as possible. Certain samples will also have added opacifier and zinc, for example.

Admittedly, stains can produce homogeneous color which can be less interesting than the variegated and speckled color effects that can be achieved with raw metal oxides like iron, cobalt, copper, etc. But for manufacturing, it cannot be ignored that stains are far more consistent and reliable to use.

Potters love to paint stains over and under glazes to decorate ware. Majolica ware is a good example. However, keep in mind that stains vary in their willingness to allow the underglaze to envelope the color particles. Some tend to crystallize the surface if used overglaze. Likewise, if stains are used underglaze they vary in their willingness to allow the overglaze to penetrate through to form and interface with the body. Stains don't suspend well in water to create a paintable material either so it is necessary to mix them with a compatible and paintable glaze medium for doing brushwork.

Stains exist either in the context of the huge industrial ceramic industry or in the hobby, pottery, and ceramics markets. Large industries either have in-house technical people or contract consultants. Small users do not have this luxury. They should know that certain stain companies, (i.e. Mason) have developed excellent reputations for dealing with smaller volumes and providing support.

A fired glaze can leach heavy metals whether these metals are sourced from a stain or from raw metal oxides. Thus you should have your glazes tested for leaching if you are making functional ware having stained food surfaces. There are many factors that determine if a glaze is leachable (for more information see links).

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XML

<?xml version="1.0" encoding="UTF-8"?>
<material name="Stains" descrip="" generic="0" rawmineral="0" searchkey="" loi="0.00">
<families>
<family name="Colorant"/>
</families>
<references>
<reference name="seealso" reason=""/>
</references>
<notes>
<note>&lt;p&gt;Thousands of body and glaze stains are available from dozens of stains companies around the world. Some companies have been in business for a hundred years or more, many specialize in creating products for a particular manufacturing sector. Some companies have multinational distribution networks, others will deal directly with small companies. Most companies have technical staff and research facilities to handle a wide range of color problems.&lt;/p&gt;

&lt;p&gt;Stains are fired blends of metal and ceramic oxides that have been reground
into a fine powder. Stains containing otherwise toxic oxides can be employed
without significant dangers. This is the first aspect of something that stains
have that coloring oxides don\'t: stability. A second aspect of stability is that
stains produce much more consistent and repeatable color than using raw oxide
colors.&lt;/p&gt;
&lt;p&gt;Stains are most popular at lower temperatures where colors tend to be
brighter. However most stains can be used right up to high fire. Premixed low
fire glazes are typically made by blending stains and commercial frits and other
than following firing instructions, users of these products give little thought
to the technical challenges that were overcome to produce them. This is a third
key advantage of stains: the ability to target a specific color. Many ceramic
color shades (i.e. reds) are difficult to achieve and beyond the abilities of
end users.&lt;/p&gt;
&lt;p&gt;While many stains are \'standard\' and their composition is well known across
the industry, others are proprietary. Stain companies don\'t release the exact
makeup of stains but they do tell us the \'system\'. For example, a green stain
might contain chrome, cobalt and silica and be labeled \'CrCoSi\'. Although silica
is not a colorant itself, it is included to create a stable silicate crystal
structure with the other two.&lt;/p&gt;
&lt;p&gt;Stain companies often supply multiple products to produce a given color using
different oxide systems (i.e. chrome-tin pink, manganese-alumina pink). Various
factors like the base glaze chemistry, color shade, temperature, and end use
determine the system you should choose. Knowing how to calculate the oxide
makeup of a glaze or dealing with a stain company that provides good service are
key factor to being able to troubleshoot color problems with stains.&lt;/p&gt;
&lt;p&gt;Thus stains do not come with a \'unconditional color guarantee\'. The shade
produced depends on many of factors including the host glaze chemistry, on/over/underglaze
use, glaze thickness, amount of opacifier, firing temperature, etc. Achieving
colors with stains is certainly easier, but it is not a \'no-brainer\'. Certain
systems are quite flexible and produce color in many kinds of glazes (ie. cobalt
silicate). Other systems either require that certain oxides be present in the
host glaze in minimum amounts or others not be present at all. The symbiosis of
host glaze chemistry and stain, for example, can be demonstrated with chrome-tin
stains. They will not develop color if zinc is present or if there is inadequate
calcia. It is common to hear people say that their pink stain \'burned out\', but
generally the stain is being used in an incompatible glaze base. Another
interesting demonstration of these factors is the color chart of a typical stain
company. These charts show the stain used in one or more fritted base glazes
that are selected to be compatible with as many of the colors as possible.
Certain samples will also have added opacifier and zinc, for example.&lt;/p&gt;
&lt;p&gt;Admittedly, stains can produce homogeneous color which can be less
interesting than the variegated and speckled color effects that can be achieved
with raw metal oxides like iron, cobalt, copper, etc. But for manufacturing, it
cannot be ignored that stains are far more consistent and reliable to use.&lt;/p&gt;
&lt;p&gt;Potters love to paint stains over and under glazes to decorate ware. Majolica
ware is a good example. However, keep in mind that stains vary in their
willingness to allow the underglaze to envelope the color particles. Some tend
to crystallize the surface if used overglaze. Likewise, if stains are used
underglaze they vary in their willingness to allow the overglaze to penetrate
through to form and interface with the body. Stains don\'t suspend well in water
to create a paintable material either so it is necessary to mix them with a
compatible and paintable glaze medium for doing brushwork.&lt;/p&gt;
&lt;p&gt;Stains exist either in the context of the huge industrial ceramic industry or
in the hobby, pottery, and ceramics markets. Large industries either have
in-house technical people or contract consultants. Small users do not have this
luxury. They should know that certain stain companies, (i.e. Mason) have
developed excellent reputations for dealing with smaller volumes and providing
support.&lt;/p&gt;
&lt;p&gt;A fired glaze can leach heavy metals whether these metals are sourced from a
stain or from raw metal oxides. Thus you should have your glazes tested for
leaching if you are making functional ware having stained food surfaces. There
are many factors that determine if a glaze is leachable (for more information
see links).&lt;/p&gt;</note>
</notes>
</material>


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